I like Tegan and Sara but I wouldn't say they are great vocally. Amanda Rogers has a pleasant voice, but I haven't heard enough to put her up there as a great vocalist. On outright vocal ability I'd have to say LeAnn Rimes, but some of my favourites are:
Cara Dillon
PP Arnold
Emiliana Torrini
Leona Naess
Beth Orton
Linda Perry (4 Non Blondes)
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