My personal favorite is "embryonic journey", by Jefferson Airplane (more specifically by their guitar virtuoso Jorma Kaukonen).
You could also throw SRV's "Lenny" on the list (love Little Wing, but that's really more Hendrix). Zeppelin's got a few but my favorite is "Bron-yr-aur" (not to be confused with Bron-yr-aur stomp).
I saw you like Rodrigo y Gabriela but you didn't include "Tamacun". Find a video of them playing it live. Asombroso!
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