Most songs by Neutral Milk Hotel or Jeff Mangum. His live performances hold a lot of emotion that you sometimes don't hear in the studio albums, such as a certain version of him playing Two Headed Boy. He also does a lot of alternate lyrics in the live sets.
Other than that, Radiohead's "I Might Be Wrong" Live EP has a lot of versions of songs that I prefer much more, Like Spinning Plates being the big one (the piano is absolutely beautiful).
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