This is almost impossible
Octovarium- Dream Theater @ 3:49 (I know it's not technically a riff,)
Welcome to the Jungle- Guns 'N Roses
Knights of Cydonia- Muse
All Along the Watchtower- Jimi Hendrix
Electric Tears- Buckethead
Ride On- AC/DC (simple, yet awesome)
Smells Like Teen Spirit- Nirvana
and so many others
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