I think the best place to start (that I know of) would be either Torch of the Mystics or Horse Cock Phepner ... those are probably my two favourites, and they're more accessible than some of the other stuff I've heard as well.
They have lots of releases but not all of them are particularly good, they released some jams they did which are basically just improvised guitar noodling sessions, and they're not very good at all. Quality control has never been Sun City Girls' strongest area, but when they're at their best, they are one of my favourite bands.
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